Quantitative Detection of Trace Explosive Vapors by Programmed Temperature Desorption Gas Chromatography-Electron Capture Detector
نویسندگان
چکیده
منابع مشابه
Fast gas chromatography of explosive compounds using a pulsed-discharge electron capture detector.
The detection of a mixture of nine explosive compounds, including nitrate esters, nitroaromatics, and a nitramine in less than 140 sec is described. The new method employs a commercially available pulsed-discharge electron capture detector (PDECD) coupled with a microbore capillary gas chromatography (GC) column in a standard GC oven to achieve on-column detection limits between 5 and 72 fg for...
متن کاملQuantitative PCB standards for electron capture gas chromatography.
電子捕獲型検出器(ECD)に よるPCBの 定量分析 は ECDがPCBの 異 性体 に対 して異な る感度 で 応答 す る ので,サ ンプル中のPCBを 塩 素化 し,す べ てを10-塩 化 ビフェニルに変 換 して得 るECD信 号 と,既 知 量 の PCB標 準物質を塩素化 して得 るECD信 号 とを比較 し てな され てい る.こ の定量法 は総PCB量 を迅速,か つ 高感度に測定 できるが,前 処理 が面倒であ り,ま たサ ン プル に代 謝ま たは分解が起 っていて も,組 成を無視 して いるので,わ か らない.そ こで各 ピー クの量的な組 成の わか ってい るPCB標 準物 質を使 った定量 分析 はこの欠 点を克服 する. 図-1にAroclor1242(モ ンサ ン ト社)のECDに よ る ク ロマ トグ ラ ムを,表1に そ の組 成 を示...
متن کاملDetermination of Isosorbide Dinitrate in Serum by Gas Chromatography with New Generation of Electron Capture Detector and its Application in Pharmacokinetic Study
Isosorbide dinitrate (ISDN) is an effective drug in treatment of angina pectoris. In this study a new generation of electron capture detector (non-radioactive) with a short, non-polar and wide-bore column was used for analysis of ISDN in human serum. ISDN was extracted from serum by a mixture of ether and ethyl acetate and concentrated at room temperature. The method was linear between 5-50...
متن کاملDetermination of Isosorbide Dinitrate in Serum by Gas Chromatography with New Generation of Electron Capture Detector and its Application in Pharmacokinetic Study
Isosorbide dinitrate (ISDN) is an effective drug in treatment of angina pectoris. In this study a new generation of electron capture detector (non-radioactive) with a short, non-polar and wide-bore column was used for analysis of ISDN in human serum. ISDN was extracted from serum by a mixture of ether and ethyl acetate and concentrated at room temperature. The method was linear between 5-50...
متن کاملDetermination of morphine by electron capture gas-liquid chromatography.
We describe a micromethod for determining as little as 0.1 microgram of morphine per liter of human urine. The procedure is about 20-fold more sensitive than are currently used gas-liquid chromatographic methods. It is particularly suitable for use as a confirmatory method for large-scale radioimmunoassay screening tests. The procedure involves extraction of morphine from urine and analysis of ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Visualized Experiments
سال: 2014
ISSN: 1940-087X
DOI: 10.3791/51938